Peanut meal-based wood adhesives enhanced by urea and epichlorohydrin

Abstract

Peanut meal (PM) has recently emerged as a potential protein source for wood adhesives, owing to superior features such as high availability, renewability and eco-friendliness. However, the poor properties of unmodified PM-based wood adhesives, compared with their petroleum-derived counterparts, limit their use in high-performance applications. In order to promote the application of PM-based wood adhesives in plywood industry, urea (U) and epichlorohydrin (ECH) were used to enhance the properties of the adhesives and the modification mechanism was investigated. PM-based wood adhesives made with U and ECH were shown to possess sufficient water resistance and exhibited higher apparent viscosity and solid content than without. Fourier-transform infrared spectroscopy results suggested that U denatured PM protein and expose more reactive groups, allowing ECH to react better with U-treated PM protein to form a dense, cross-linked network which was the main reason for the improvement of the properties. The crystallinity increased from 2.7% to 11% compared with the control, indicating that the molecular structure of the resultant adhesive modified by U and ECH became more regular and compact owing to the cross-linked network structure. Thermogravimetry tests showed that decomposition temperature of the protein skeleton structure increased from 307°C to 314°C after U and ECH modification. Scanning electron microscopy images revealed that using U and ECH for adhesives resulted in a smooth protein surface which prevented moisture penetration and improved water resistance. PM-based adhesives thus represent potential candidates to replace petroleum-derived adhesives in the plywood industry, which will effectively promote the rapid development of eco-friendly adhesives and increase the added value of PM.