Performance investigation of poly(vinylidene fluoride-cohexafluoropropylene) membranes containing SiO2 nanoparticles in a newly designed single vacuum membrane distillation system

Abstract

The current study focuses on the development of a superhydrophobic poly(vinylidene fluoride-cohexafluoropropylene) nanocomposite membrane suitable for vacuum membrane distillation by incorporating SiO2 nanoparticles. At loading hydrophobic nano-SiO2 particle concentration (0.50–1.50 wt.%), the developed nanocomposite membranes are optimized in terms of vacuum membrane distillation performance. The influence of temperature, vacuum pressure, and feed water flow is studied for desalinating high-salinity brine. The results show that the developed vacuum distillation membrane is capable of 95% salt rejection during the treatment of a highly saline feed (65,000 ppm) at fixed flow rates of 120 L/h saline feed and different operating conditions consisting of feed inlet temperatures ranging from 40°C to 70°C and distillate inlet temperatures of 7–15°C. The vacuum membrane distillation process achieves 0.38–1.66% water recovery with increasing concentration factor, meaning that recovery is increased, and shows a specific electrical energy consumption of 5.16–23.90 kWh/m3 for product water. Overall, the newly designed membrane demonstrates suitability for a vacuum membrane distillation system. Practitioner Points: Desalinate high-salinity brine (TDS > 35,000 ppm) using a vacuum membrane distillation system. A hydrophobic PVDF-HFP/SiO2 nanocomposite membrane development for vacuum membrane distillation. A newly designed single vacuum membrane distillation system for RO brine treatment.