Tailoring Activated Carbons for Efficient Downstream Processing: Selective Liquid-Phase Adsorption of Lysine

Abstract

The essential amino acid lysine is of great importance in the nutrition and pharmaceutical industries and is mainly produced in biorefineries by the fermentation of glucose. In biorefineries, downstream processing is often the most energy-consuming step. Adsorption on hydrophobic adsorbents represents an energy, resource, and cost-saving alternative. The results reported herein provide insights into the selective separation of l-lysine from aqueous solution by liquid-phase adsorption using tailored activated carbons. A variety of commercial activated carbons with different textural properties and surface functionalities is investigated. Comprehensive adsorbent characterization establishes structure–adsorption relationships that define the major roles of the specific surface area and oxygen functionalities. A 13-fold increase of the separation of lysine and glucose is achieved through systematic modification of a selected activated carbon by oxidation, and lysine adsorption is enhanced by 30 %.