Chiral MOP-phosphonite ligands: Synthesis, characterisation and interconversion of η1,η6-(σ-P, π-arene) chelated rhodium(i) complexes

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Abstract

The synthesis of rhodium(i) and iridium(i) complexes of chiral MOP-phosphonite ligands is reported. The full characterisation of η1,η6-(σ-P, π-arene) chelated 18VE rhodium(i) complexes reveals hemilabile binding on the arene which has been quantitatively analysed. © 2013 The Royal Society of Chemistry.

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Ficks, A., Harrington, R. W., & Higham, L. J. (2013). Chiral MOP-phosphonite ligands: Synthesis, characterisation and interconversion of η1,η6-(σ-P, π-arene) chelated rhodium(i) complexes. Dalton Transactions, 42(18), 6302–6305. https://doi.org/10.1039/c3dt50482d

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