Carbon-Halogen Bond Activation with Powerful Heavy Alkaline Earth Metal Hydrides

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Abstract

Reaction of [(DIPePBDI)SrH]2 with C6H5X (X=Cl, Br, I) led to hydride-halogenide exchange (DIPePBDI=HC[(Me)CN-2,6-(3-pentyl)phenyl]2). Conversion rates increase with increasing halogen size (F

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Wiesinger, M., Rösch, B., Knüpfer, C., Mai, J., Langer, J., & Harder, S. (2021). Carbon-Halogen Bond Activation with Powerful Heavy Alkaline Earth Metal Hydrides. European Journal of Inorganic Chemistry, 2021(36), 3731–3741. https://doi.org/10.1002/ejic.202100529

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