Large deviations and the equivalence of ensembles for Gibbsian particle systems with superstable interaction

Abstract

For Gibbsian systems of particles in Rd, we investigate large deviations of the translation invariant empirical fields in increasing boxes. The particle interaction is given by a superstable, regular pair potential. The large deviation principle is established for systems with free or periodic boundary conditions and, under a stronger stability hypothesis on the potential, for systems with tempered boundary conditions, and for tempered (infinite-volume) Gibbs measures. As a by-product we obtain the Gibbs variational formula for the pressure. We also prove the asymptotic equivalence of microcanonical and grand canonical Gibbs distributions and establish a variational expression for the thermodynamic entropy density. © 1994 Springer-Verlag.