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Selective oxidative hydroxylation of arylboronic acids by colloidal nanogold catalyzed in situ generation of H2O2 from alcohols under aerobic conditions

Bulletin of the Chemical Society of Japan (2020) 93(2) 299-301
DOI: 10.1246/BCSJ.20190265
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Abstract

Selective hydroxylation of arylboronic acids was achieved through PVP (polyvinylpyrrolidone)-stabilized nanogold catalyzed in situ generated H2O2 formed by the oxidation of an alcoholic solvent under aerobic conditions. The synthetic application of in situ generated H2O2 was investigated through aerobic epoxidation of (E)-chalcone.

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Vinsen, Y. U., & Sakurai, H. (2020). Selective oxidative hydroxylation of arylboronic acids by colloidal nanogold catalyzed in situ generation of H2O2 from alcohols under aerobic conditions. Bulletin of the Chemical Society of Japan, 93(2), 299–301. https://doi.org/10.1246/BCSJ.20190265

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