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Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization

  • Carreras J
  • Kirillova M
  • Echavarren A
Angewandte Chemie (2016) 128(25) 7237-7241
DOI: 10.1002/ange.201601834
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Abstract

The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)‐catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.

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Carreras, J., Kirillova, M. S., & Echavarren, A. M. (2016). Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization. Angewandte Chemie, 128(25), 7237–7241. https://doi.org/10.1002/ange.201601834

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