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Total synthesis of photosynthetic pigment fucoxanthin by use of oxo-metallic catalyst

Chemical and Pharmaceutical Bulletin (1994) 42(2) 410-412
DOI: 10.1248/cpb.42.410
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Abstract

The first total synthesis of optically active fucoxanthin 1 has been accomplished via the 8-oxo-compound 7, efficiently prepared by rearrangement of the a-acetylenic alcohol 2 using oxo-metallic catalyst and subsequent iodine catalyzed double bond-shift. © 1994, The Pharmaceutical Society of Japan. All rights reserved.

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Yamano, Y., & Ito, M. (1994). Total synthesis of photosynthetic pigment fucoxanthin by use of oxo-metallic catalyst. Chemical and Pharmaceutical Bulletin, 42(2), 410–412. https://doi.org/10.1248/cpb.42.410

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