Photochemistry and vertical transport in Io's atmosphere and ionosphere

Abstract

We present an updated model for the photochemistry of Io's atmosphere and ionosphere and use this model to investigate the sensitivity of the chemical structure to vertical transport rates. SO2 is assumed to be the dominant atmospheric gas, with minor molecular sodium species such as Na2S or Na2O released by sputtering or venting from the surface. Photochemical products include SO, O2, S, O, Na, NaO, NaS, and Na2. We consider both "thick" and "thin" SO2 atmospheres that encompass the range allowed by recent HST and millimeter-wave observations, and evaluate the possibility that O2 and/or SO may be significant minor dayside constituents and therefore likely dominant nightside gases. The fast reaction between S and O2 limits the column abundance of O2 to ∼104 less than that calculated by Kumar (J. Geophys. Res. 87, 1677-1684, 1982; 89(A9), 7399-7406,1984) for a pure sulfur/oxygen atmosphere. If a significant source of NaO2 or Na2O were supplied by the surface and mixed rapidly upward, then oxygen liberated in the chemical reactions which also liberate free Na would provide an additional source of O2. Fast eddy mixing will enhance the transport of molecular sodium species to the exobase, in addition to increasing the vertical transport rate of ions. Ions produced in the atmosphere will be accelerated by the reduced corotation electric field penetrating the atmosphere. These ions experience collisions with the neutral gas, leading to enhanced vertical ion diffusion. The dominant ion, Na+, is lost primarily by charge exchange with Na2O and/or Na2S in the lower atmosphere and by diffusion through the ionopause in the upper atmosphere. The atmospheric column abundance of SO, O2, and the upper atmosphere escape rates of Na, S, O, and molecular sodium species are all strong functions of the eddy mixing rate. Most atmospheric escape, including that of molecular sodium species, probably occurs from the low density "background" SO2 atmosphere, while a localized high density "volcanic" SO2 atmosphere can yield an ionosphere consistent with that detected by the Pioneer 10 Spacecraft. © 1996 Academic Press, Inc.