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Ion-size-dependent formation of mixed titanium/lanthanide oxo clusters

European Journal of Inorganic Chemistry (2014) 2014(32) 5596-5602
DOI: 10.1002/ejic.201402670
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Abstract

The mixed-metal oxo clusters LnTi4O3(OiPr)2(OMc)11 (Ln = La, Ce; OMc = methacrylate), Ln2Ti6O6(OMc)18(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln2Ti4O4(OMc)14(HOMc)2 (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion.

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Artner, C., Kronister, S., Czakler, M., & Schubert, U. (2014). Ion-size-dependent formation of mixed titanium/lanthanide oxo clusters. European Journal of Inorganic Chemistry, 2014(32), 5596–5602. https://doi.org/10.1002/ejic.201402670

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