Synthesis, characterization, and optimization of magnetoelectric BaTiO3 –iron oxide core–shell nanoparticles

Abstract

Improvement of magnetic, electronic, optical, and catalytic properties in cutting-edge technologies including drug delivery, energy storage, magnetic transistor, and spintronics requires novel nanomaterials. This article discusses the unique, clean, and homogeneous physiochemical synthesis of BaTiO3 /iron oxide core–shell nanoparticles with interfaces between ferroelectric and ferromagnetic materials. High-resolution transmission electron microscopy displayed the distinguished disparity between the core and shell of the synthesized nanoparticles. Elemental mapping and line scan confirmed the formation of the core–shell structure. Energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy detected the surface iron oxide phase as maghemite. Rietveld analysis of the X-ray diffraction data labeled the crystallinity and phase purity. This study provides a promising platform for the desirable property development of the futuristic multifunctional nanodevices.