Abstract
In order to clarify the conformation of chromophore in rhodopsin, especially the torsional angle around the C6-C7 single bond, 8,18-propano- and methano-retinals were prepared from 2,2-dimethylcyclohexanone via the palladium-catalyzed coupling reaction of vinyl triflates with methyl E-3-trimethylstannyl-2-butenoate, and their interaction with bovine opsin was investigated. © 1995, The Pharmaceutical Society of Japan. All rights reserved.
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Wad, A., Tsutsumi, M., Inatomi, Y., Ito, M., Imai, H., & Shichida, Y. (1995). Synthesis of 11Z-8,18-Propano- and Methano-Retinals and Their Interaction with Bovine Opsin. Chemical and Pharmaceutical Bulletin, 43(8), 1419–1421. https://doi.org/10.1248/cpb.43.1419
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