A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes

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Abstract

A new methodology for the direct C-H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl-Au(i) compounds without the need for using Ag(i) additives or preparing and isolating basic Au(i) hydroxide complexes. © 2013 The Royal Society of Chemistry.

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Ahlsten, N., Perry, G. J. P., Cambeiro, X. C., Boorman, T. C., & Larrosa, I. (2013). A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes. Catalysis Science and Technology, 3(11), 2892–2897. https://doi.org/10.1039/c3cy00240c

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