Abstract
A novel photoswitchable rotaxane was synthesised and its switching behaviour in solution was analysed with NMR and UV-Vis. A monolayer of rotaxanes was deposited on glass surfaces and the on-surface photoswitching was investigated. Angle-resolved NEXAFS spectra revealed a preferential orientation that reversibly changes upon switching.
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CITATION STYLE
APA
Schwarz, F. B., Heinrich, T., Lippitz, A., Unger, W. E. S., & Schalley, C. A. (2016). A photoswitchable rotaxane operating in monolayers on solid support. Chemical Communications, 52(100), 14458–14461. https://doi.org/10.1039/c6cc08586e
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