Abstract
The steroid 3, with three independently-addressable, rigidly-positioned functional groups, has been synthesized in an efficient, multi-gram sequence from inexpensive cholic acid 1. Compound 3 should prove valuable as a starting point for combinatorial libraries with preorganised, co-directed arrays of substituents.
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Barry, J. F., Davis, A. P., Pérez-Payan, M. N., Elsegood, M. R. J., Jackson, R. F. W., Gennari, C., … Gude, M. (1999). A trifunctional steroid-based scaffold for combinatorial chemistry. Tetrahedron Letters, 40(14), 2849–2852. https://doi.org/10.1016/S0040-4039(99)00309-3
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