Scanning electrochemical cell microscopy with a single barrel micro-/nano-pipette (SECCM) was applied to lithium iron phosphate (LiFePO4) composite positive electrodes and an isolated LiFePO4 secondary particle for lithium-ion batteries. To analyze lithium-ion (Li+) charge or discharge process on the electrodes using local probe, a pipette filled with LiCl electrolyte solution and Ag/AgCl quasi-reference counter electrode (QRCE) was used. Both the local electrochemical activities of LiFePO4 on the composite electrodes and a single particle were revealed by SECCM as in-situ direct measurement of current response-related Li+ transport from mapping and cyclic voltammogram at confined area by the pipette. The mapping has visualized Li+ deintercalation process from LiFePO4 at +0.65 V (applied between the sample-QRCE). We show that the SECCM system is a strong analytical tool for a characterization of local Li+ behavior of active electrode materials in lithium-ion batteries.
CITATION STYLE
Kumatani, A., Takahashi, Y., Miura, C., Ida, H., Inomata, H., Shiku, H., … Matsue, T. (2019). Scanning electrochemical cell microscopy for visualization and local electrochemical activities of lithium-ion (de) intercalation process in lithium-ion batteries electrodes. Surface and Interface Analysis, 51(1), 27–30. https://doi.org/10.1002/sia.6538
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