The homogeneous nucleation of 1-pentanol in a laminar flow diffusion chamber: The effect of pressure and kind of carrier gas

Abstract

The influence of total pressure and kind of carrier gas on homogeneous nucleation rates of 1-pentanol was investigated using experimental method of laminar flow diffusion chamber in this study. Two different carrier gases (helium and argon) were used in the total pressure range from 50 to 400 kPa. Nucleation temperatures ranged from 265 to 290 K for 1-pentanol-helium and from 265 to 285 K for 1-pentanol-argon. Nucleation rates varied between 101 and 106 cm-3 s-1 for 1-pentanol-helium and between 102 and 105 cm-3 s-1 for 1-pentanol-argon. Both positive and slight negative pressure effects were observed depending on temperature and carrier gas. The trend of pressure effect was found similar for both carrier gases. Error analysis on thermodynamic properties was conducted, and the lowering of surface tension due to adsorption of argon on nucleated droplets was estimated. A quantitative overview of pressure effect is provided. © 2008 American Institute of Physics.