Abstract
"Catch-and-release": Simple alk-1-enes are effective at liberating buta-1,3-dienes from vinyl alkylidene ruthenium complexes, as well as undergoing alkene-alkylidene exchange with enyne substrates to regenerate the alk-1-ene. This ability to "catch-andrelease" ruthenium alkylidenes allows alk-1-enes higher than ethylene ("Mori's conditions") to be used as a co-catalysts in terminal enyne metathesis with the Grubbs generation I complex (L=PCy3). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Author supplied keywords
Cite
CITATION STYLE
Lloyd-Jones, G. C., Robinson, A. J., Lefort, L., & De Vries, J. G. (2010). A simple and effective co-catalyst for ring-closing enyne metathesis using Grubbs I type catalysts: A practical alternative to “Mori’s conditions.” Chemistry - A European Journal, 16(31), 9449–9452. https://doi.org/10.1002/chem.201001510
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
