Propane Dehydrogenation over PtSn/Al2O3 Catalysts: Influence of Urea to Al(NO3)3·9H2O Ratio

Abstract

Al2O3 supports were synthesized by the hydrothermal method and PtSn/Al2O3 catalysts were prepared by incipient-wetness impregnation method. The influence of the ratio of urea to Al(NO3)3·9H2O on the structure and catalytic performance for propane dehydrogenation was investi-gated. The catalysts were characterized by XRD, N2 adsorption–desorption, SEM, H2-TPR, NH3-TPD and Raman. The results show that the ratios of urea to Al(NO3)3·9H2O influence the morphology and phy-chemical properties of Al2O3 support, which influence the dispersion of PtSn active sites and the interaction of Pt and Sn on PtSn/Al2O3 catalysts. The PtSn/Al2O3-9 catalyst possesses the highest interaction of Pt and Sn, which result in high dispersion of active sites. The PtSn/Al2O3-9 catalyst shows high propane conversion and low deactivation rate among these catalysts.