Abstract
The photochemical reactivity of osmocene in a biphasic waterorganic solvent system has been investigated to probe its water splitting properties. The photoreduction of aqueous protons to hydrogen under anaerobic conditions induced by osmocene dissolved in 1,2-dichloroethane and the subsequent water splitting by the osmocenium metal-metal dimer formed during H2 production were studied by electrochemical methods, UV-visible spectrometry, gas chromatography, and nuclear magnetic resonance spectroscopy. Density functional theory computations were used to validate the reaction pathways.
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CITATION STYLE
Ge, P., Todorova, T. K., Patir, I. H., Olaya, A. J., Vrubel, H., Mendez, M., … Girault, H. H. (2012). Biphasic water splitting by osmocene. Proceedings of the National Academy of Sciences of the United States of America, 109(29), 11558–11563. https://doi.org/10.1073/pnas.1203743109
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