Characteristics of chlorine releasing from coal-fired power plant

Abstract

Chlorine (Cl) released from coal-fired power plants can be harmful to power equipment, the ecological environment and human health. Here, we investigated the Cl releasing characteristics from four coal-fired power plants (CFPPs) in China’s Anhui province based on an ion chromatography analysis of the combustion by-production samples collected from different locations of the power plants. The results showed that Cl content in coals was low (198–367 µg·g−1), which positively correlated with the contents of lead, mercury and total sulfur, but was weakly correlated with the moisture and ash yield in coal. The releasing rate of Cl during coal combustion was highly correlated with temperature and volatile matter, and most Cl is transferred into the flue gas. Dust collector and wet flue gas devices equipped in the CFPPs were robust for removing Cl in the particulate phase, and the fabric filter showed a higher removal efficiency than the electrostatic precipitator. This study can provide theoretical support for Cl pollution control in coal-fired power plants.