Abstract
Tune it with light! Self-assembled monolayers on gold based on a chemisorbed novel azobenzene derivative with a perfluorinated terminal phenyl ring are prepared. The modified substrate shows a significant work function increase compared to the bare metal. The photo-conversion between trans and cis isomers chemisorbed on the surface shows great perspectives for being an accessible route to tune the gold properties by means of light. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Crivillers, N., Osella, S., Van Dyck, C., Lazzerini, G. M., Cornil, D., Liscio, A., … Samorì, P. (2013). Large work function shift of gold induced by a novel perfluorinated azobenzene-based self-assembled monolayer. Advanced Materials, 25(3), 432–436. https://doi.org/10.1002/adma.201201737
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