Abstract
We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2- ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
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CITATION STYLE
APA
Santoru, A., Pistidda, C., Sørby, M. H., Chierotti, M. R., Garroni, S., Pinatel, E., … Dornheim, M. (2016). KNH2-KH: A metal amide-hydride solid solution. Chemical Communications, 52(79), 11760–11763. https://doi.org/10.1039/c6cc05777b
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