Study on Hydrogen Embrittlement Behavior of X65 Pipeline Steel in Gaseous Hydrogen Environment

Abstract

Pipeline steel is highly susceptible to hydrogen embrittlement (HE) in hydrogen environments, which compromises its structural integrity and operational safety. Existing studies have primarily focused on the degradation trends of mechanical properties in hydrogen environments, but there remains a lack of quantitative failure prediction models. To investigate the failure behavior of X65 pipeline steel under hydrogen environments, this paper utilized notched round bar specimens with three different radii and smooth round bar specimens to examine the effects of pre-charging time, the coupled influence of stress triaxiality and hydrogen concentration, and the coupled influence of strain rate and hydrogen concentration on the HE sensitivity of X65 pipeline steel. Fracture surface morphologies were characterized using scanning electron microscopy (SEM), revealing that hydrogen-enhanced localized plasticity (HELP) dominates failure mechanisms at low hydrogen concentrations, while hydrogen-enhanced decohesion (HEDE) becomes dominant at high hydrogen concentrations. The results demonstrate that increasing stress triaxiality or decreasing strain rate significantly intensifies the HE sensitivity of X65 pipeline steel. Based on the experimental findings, failure prediction models for X65 pipeline steel were developed under the coupled effects of hydrogen concentration and stress triaxiality as well as hydrogen concentration and strain rate, providing theoretical support and mathematical models for the engineering application of X65 pipeline steel in hydrogen environments.