Asymmetric inter- and intramolecular cyclopropanation reactions catalyzed by a reusable macroporous-polymer-supported chiral ruthenium(II)/phenyloxazoline complex

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Abstract

Along came poly: A novel macroporous polymer-supported chiral Ru II/pheox catalyst (1, see SEM image) afforded excellent reactivity and enantioselectivity in inter- and intramolecular cyclopropanation reactions with a broad range of substrates. The catalyst showed no leaching and could be reused up to 11-times, even after storage. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Abu-Elfotoh, A. M., Phomkeona, K., Shibatomi, K., & Iwasa, S. (2010). Asymmetric inter- and intramolecular cyclopropanation reactions catalyzed by a reusable macroporous-polymer-supported chiral ruthenium(II)/phenyloxazoline complex. Angewandte Chemie - International Edition, 49(45), 8439–8443. https://doi.org/10.1002/anie.201002240

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