Provenance study of prehistoric ceramics from sicily: A comparative study between pXRF and XRF

Abstract

The 1964 archaeological exploration of the Ognina islet near Syracuse, Sicily, has provided evidence suggesting a long-term prehistoric occupation from the Neolithic to the Middle Bronze Age. Maltese style ceramics were found in Early and Middle Bronze Age layers. A small group of imports belonging to the Thermi Ware culture was found in connection with the local Castelluccian Ware (EBA), and Maltese style Bor. in-Nadur wares were recovered with local Thapsos ceramics (MBA). During fieldwork in 2012, large amounts of ceramics were recovered including new examples of Thermi and Bor. in-Nadur wares as well as large amounts of Castelluccian and Thapsos pottery. In order to ascertain whether the Maltese type pottery was imported from Malta, a program of archaeometric analyses was established. Diagnostic samples belonging to both Maltese-like and Sicilian pottery classes were analyzed with destructive thin sectioning and X-ray fluorescence spectrometry (XRF) and subsequently analyzed with non-destructive portable X-ray fluorescence spectrometry (pXRF) together with a sample of Sicilian clay taken from a clay source close to the islet. The analyses demonstrated that the two Thermi Ware samples were locally produced and three out of four Bor. in-Nadur pieces had a Maltese provenance while one of the four being produced in Sicily.