Zinc oxide quantum rods

Abstract

Nanoscale zinc oxide (ZnO) rods of diameters close to the Bohr-exciton radius (∼2 nm) can be prepared from a simple acetate precursor, resulting in ligand-capped rods of ZnO, highly dispersible in nonpolar solvents. Zinc oxide, ZnO, is a wide band-gap semiconductor with applications in blue/ultraviolet (UV) optoelectronic devices and piezoelectric devices. We observe self-assembly into uniform stacks of nanorods aligned parallel to each other with respect to the long axis, and photoluminescence measurements provide evidence for one-dimensional quantum confinement. Copyright © 2003 American Chemical Society.