Optimizing Heat Treatment Conditions for Measuring CFRP and GFRP Resin Impregnation

Abstract

As the use of carbon-fiber-reinforced plastic (CFRP) and glass-fiber-reinforced plastic is frequent in the field of construction, a method for measuring FRP resin content is needed. Herein, thermal gravimetric analysis (TGA) was employed to optimize the heat treatment conditions (temperature and time) for determining the resin content in which only the resin was removed without fiber heat loss. Accordingly, the measurement was performed in 100 °C increments at a resin pyrolysis temperature up to 800 °C with a heat treatment time of 4 h to continuously observe the degree of thermal decomposition of the resin. The thermal decomposition of unsaturated polyester was confirmed at the melting point (350 ℃) regardless of the type of fibers used as reinforcement. In the case of CFRP, most of the resin decomposition occurred at 300 °C. Notably, the resin was removed at a pyrolysis temperature of 400 ℃ and almost no change in weight was observed. However, at a pyrolysis temperature of 500 °C or higher, the thermal decomposition of the fibers occurred partially. The results show that the composite resin was removed within 10 min at a pyrolysis temperature of 400 °C in an air atmosphere when using TGA.