Sr[sub 3−x]La[sub x]Fe[sub 2−y]Co[sub y]O[sub 7−δ] (0.3≤x≤0.6 and 0≤y≤0.6) Intergrowth Oxide Cathodes for Intermediate Temperature Solid Oxide Fuel Cells

Abstract

The perovskite-related intergrowth oxides, Sr3-x Lax Fe2-y Coy O7-δ (0.3≤x≤0.6 and 0≤y≤0.6), have been investigated as cathode materials for intermediate temperature solid oxide fuel cells. With a given La content x, the electrical conductivity, oxide-ion vacancy concentration, and thermal expansion coefficient (TEC) increase with increasing Co content y. With a given Co content, while the electrical conductivity increases, the TEC decreases with increasing La content. The electrocatalytic activity and power density measured with Sr3-x Lax Fe2-y Coy O7-δ La0.8 Sr0.2 Ga0.8 Mg0.2 O2.8 Ni- Ce0.9 Gd0.1 O1.95 (GDC) single cells with a GDC interlayer between the cathode and electrolyte increase with increasing Co and La contents due to an increase in electrical conductivity and oxide ion vacancy concentration. The electrical conductivity, TEC, and electrochemical performance of the Sr3-x Lax Fe2-y Coy O7-δ cathodes are also compared with those of the La Sr3 Fe3-y Coy O10-δ intergrowth and La0.6 Sr0.4 Co O3-δ perovskite oxides. © 2006 The Electrochemical Society. All rights Reserved.