First principle insights of NO2detection via III-V nitride nanoribbons with armchair edges

Abstract

The development of low-dimensional and robust nano-sensors is an area of potential research and development. In this direction, here, we investigated the sensing of NO2 gas molecules adsorbed on the edges of III-V nitride nanoribbons with armchair edges (AXNNR, X = B/Al/Ga). Five different adsorption sites are considered for the adsorption of NO2 molecules and the adsorption assisted modulation of electronic and transport properties has been observed for detection purpose. Interestingly, a semiconducting to metallic transition has been noticed in considered AXNNR due to NO2 interaction. The selectivity of NO2 with respect to N2 is found to be higher as compared to that of O2. Further, some of the selected structures exhibit an interesting negative differential resistance (NDR) phenomenon which suggest that NO2 adsorbed AXNNR could also be useful for designing of the fast switching devices and oscillators applications.