Low-Temperature Ag/Pd-catalyzed decarboxylative cross-coupling of aryl trflates with aromatic carboxylate salts

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Abstract

Chemical Equation Presented At 50°C lower than the best known copper catalysts, a catalytic silver(I)/ palladium(II) system allows the decarboxylative cross-coupling of arenecarboxylates with aryl triflates at temper-atures as low as 120°C. Remarkably, polychlorinated and many heterocyclic arenecarboxylates are converted for the first time in high yields. FG = functional group. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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Gooßen, L. J., Lange, P. P., Rodriguez, N., & Linder, C. (2010). Low-Temperature Ag/Pd-catalyzed decarboxylative cross-coupling of aryl trflates with aromatic carboxylate salts. Chemistry - A European Journal, 16(13), 3906–3909. https://doi.org/10.1002/chem.200903319

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