Abstract
Engagement ring: α-Metalated by a lithium bisamido-bisalkylaluminate base, the sensitive cycloanionic ring of THF or THTP remains intact by engaging with both metal centers of the base residue (see structure; X=O, S). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Crosbie, E., García-Álvarez, P., Kennedy, A. R., Klett, J., Mulvey, R. E., & Robertson, S. D. (2010). Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures. Angewandte Chemie - International Edition, 49(49), 9388–9391. https://doi.org/10.1002/anie.201005119
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