Fabrication of Bio-Nanocomposite Packaging Films with PVA, MMt Clay Nanoparticles, CNCs, and Essential Oils for the Postharvest Preservation of Sapota Fruits

Abstract

Sapota is an important climacteric fruit with limited shelf life. A special system must be employed to extend the shelf life of sapota fruits. In the present study, polyvinyl alcohol (PVA) and montmorillonite clay (MMt)-based bio-nanocomposite films (BNFs) were integrated at various concentrations (2%, 4%, 6%, and 8%) into cellulose nanocrystals (CNCs), produced from garlic peels (GPs). The BNF loaded with 8% CNC has a better crystallinity index and mechanical properties than the other concentrations of CNC. Therefore, the 8% CNC-incorporated BNF (BNF-8) was selected for further packaging studies. The combined effect of BNF-8 with ajwain essential oil (AO) and oregano essential oil (OO) vapors and BNF-8 with carbendazim (commercial fungicide-CARB) were investigated. In this study, the BNF-based packagings are categorized into five types, viz: BNF+8% CNC (BNF-8), BNF-8+AO, BNF-8+OO, BNF-8+CARB and the non-packaged fruits (control). The shelf-life duration, antioxidant activity, firmness, decay index, and sensory quality were evaluated in order to identify the effectiveness of packaging treatment on sapota fruits. BNF-8+CARB, BNF-8+AO, and BNF-8+OO packaging extended the shelf life of sapota fruits to up to 12 days and maintained the overall physiochemical parameters and sensory qualities of the fruits. Therefore, the BNF-8+AO and BNF-8+OO packaging materials are appropriate alternatives to commercial fungicides for the preservation of sapota during postharvest storage.