A [2] Catenane Made to Order

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Abstract

A template‐controlled, one‐pot reaction afforded the [2]catenane 1 in 70% yield. Compound 1 consists of π‐electron‐rich decaoxa[13.13]paracyclophane (empty circles) and an electron‐deficient macrocycle made up of two paraquat p‐phenylene units (filled circles). Dynamic 1 H NMR spectroscopy and cyclovoltammetry showed that 1 is highly ordered not only in the solid state but also in solution. (Figure Presented.) Copyright © 1989 by VCH Verlagsgesellschaft mbH, Germany

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Ashton, P. R., Goodnow, T. T., Kaifer, A. E., Reddington, M. V., Slawin, A. M. Z., Spencer, N., … Williams, D. J. (1989). A [2] Catenane Made to Order. Angewandte Chemie International Edition in English, 28(10), 1396–1399. https://doi.org/10.1002/anie.198913961

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