Scalable synthesis of WS2 on graphene and h-BN: An all-2D platform for light-matter transduction

Abstract

By exhibiting a measurable bandgap and exotic valley physics, atomically thick tungsten disulfide (WS2) offers exciting prospects for optoelectronic applications. The synthesis of continuousWS2 films on other two-dimensional (2D) materials would greatly facilitate the implementation of novel all-2D photoactive devices. In this work we demonstrate the scalable growth of WS2 on graphene and hexagonal boron nitride (h-BN) via a chemical vapor deposition approach. Spectroscopic and microscopic analysis reveal that the film is bilayer-thick, with local monolayer inclusions. Photoluminescence measurements show a remarkable conservation of polarization at room temperature peaking 74% for the entireWS2 film. Furthermore, we present a scalable bottom-up approach for the design of photoconductive and photoemitting patterns.