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Acid-base catalysis using chiral palladium complexes

Pure and Applied Chemistry (2006) 78(2) 477-494
DOI: 10.1351/pac200678020477
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Abstract

Chiral Pd aqua and μ-hydroxo complexes were found to act as mild Br0nsted acids and bases, and chiral Pd enolates were generated from these complexes even under acidic conditions. Highly enantioselective Michael addition, Mannich-type reaction, fluorination, and conjugate addition of amines have been developed based on the acid-base character of these Pd complexes. © 2006 IUPAC.

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Sodeoka, M., & Hamashima, Y. (2006). Acid-base catalysis using chiral palladium complexes. In Pure and Applied Chemistry (Vol. 78, pp. 477–494). https://doi.org/10.1351/pac200678020477

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