Abstract
A new lithium vanadium fluoride Li2VF6 was prepared by reacting lithium fluoride LiF with vanadium tetrafluoride VF4 in a monel capsule at 500 C. The crystal structure has been determined by means of powder X-ray diffraction. Trirutile-type dilithium hexafluorovanadate(IV) crystallizes in the tetragonal space group P42=mnm with lattice parameters a=459.99(1), b=459:99(1), c=896.64(2) pm. The presence of a Jahn-Teller effect is discussed. © 2014, Verlag der Zeitschrift für Naturforschung. All rights reserved.
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Nakhal, S., Weber, D., & Lerch, M. (2013). Preparation and Crystal Structure of a New Lithium Vanadium Fluoride Li2VF6 with Trirutile-type Structure. Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences, 68(2), 121–126. https://doi.org/10.5560/znb.2013-2303
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