Electrochemically tunable thermal conductivity of lithium cobalt oxide

Abstract

Using time-domain thermoreflectance, the thermal conductivity and elastic properties of a sputter deposited LiCoO2 film, a common lithium-ion cathode material, are measured as a function of the degree of lithiation. Here we report that via in situ measurements during cycling, the thermal conductivity of a LiCoO2 cathode reversibly decreases from ∼5.4 to 3.7Wm -1 K-1, and its elastic modulus decreases from 325 to 225 GPa, as it is delithiated from Li1.0CoO2 to Li 0.6CoO2. The dependence of the thermal conductivity on lithiation appears correlated with the lithiation-dependent phase behaviour. The oxidation-statedependent thermal conductivity of electrolytically active transition metal oxides provides opportunities for dynamic control of thermal conductivity and is important to understand for thermal management in electrochemical energy storage devices. © 2014 Macmillan Publishers Limited. All rights reserved.