Synthesis of symmetric trisannelated benzenes and 1,3,5-trimethylbenzene using a SOCI2/EtOH reagent

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Abstract

A simple and efficient method for the synthesis of symmetric trisannelated benzenes and 1,3,5-trimethylbenzene is presented. Two trisannelated benzenes and 1,3,5-trimethylbenzene were synthesised from cyclohexanone, cyclopentanone and acetone respectively in the presence of thionyl chloride in anhydrous ethanol.

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Hu, Z., Dong, Z., Liu, J., Liu, W., & Zhu, X. (2005). Synthesis of symmetric trisannelated benzenes and 1,3,5-trimethylbenzene using a SOCI2/EtOH reagent. Journal of Chemical Research, (4), 252–253. https://doi.org/10.3184/0308234054213546

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