Exotic exciton-phonon states and bottleneck for self-trapping

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Abstract

In a previous paper the conventional barrier model of excitonic self-trapping has been shown to display divergencies. In the present work we report on novel "exotic" exciton-phonon states, which have not been noted so far. These states are of non-self-trapping nature, and by way of their small extension in Q space they may acquire a "bottleneck" role in the process of energy dissipation. This seems to allow for a new explanation of the fast luminescence found in rare gas and other crystals. © 1990 American Institute of Physics.

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Köngeter, A., & Wagner, M. (1990). Exotic exciton-phonon states and bottleneck for self-trapping. The Journal of Chemical Physics, 92(7), 4003–4011. https://doi.org/10.1063/1.457814

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