Abstract
The title compound has been synthesized under 4 GPa and at 500 °C from Na2O andMnO as starting materials. Rietveld refinement of the X-ray powder pattern indicates that Na6MnO4 is isostructural to Na6ZnO4 and thus is representing the second manifestation of an "isolated" [MnO4]6- anion after Na 14Mn2O9. The compound crystallizes in the hexagonal system in space group P63mc (no. 186) with a = 7.6631(2) and c = 5.9013(2) Å, V = 300.1 Å3, and Z = 2. © 2009 Verlag der Zeitschrift f̈ur Naturforschung.
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Pfeiffer, S., & Jansen, M. (2009). High-pressure-high-temperature synthesis of Na6MnO4. Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences, 64(5), 487–490. https://doi.org/10.1515/znb-2009-0502
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