Abstract
A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.
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Liu, Z. L., Yang, C., Xue, Q. Y., Zhao, M., Shan, C. C., Xu, Y. H., & Loh, T. P. (2019). Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes. Angewandte Chemie - International Edition, 58(46), 16538–16542. https://doi.org/10.1002/anie.201908343
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