Probing transient hydrate structures with hyperpolarized 129Xe NMR spectroscopy: A metastable structure II hydrate of Xe

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Abstract

When hyperpolarized xenon is placed in contact with a structure II hydrate of THF, Xe NMR spectroscopy shows that a metastable structure II hydrate of Xe (see picture) forms that decomposes to a structure I Xe hydrate and a mixed structure II hydrate of xenon and THF.

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Moudrakovski, I. L., Ratcliffe, C. I., & Ripmeester, J. A. (2001). Probing transient hydrate structures with hyperpolarized 129Xe NMR spectroscopy: A metastable structure II hydrate of Xe. Angewandte Chemie - International Edition, 40(20), 3890–3892. https://doi.org/10.1002/1521-3773(20011015)40:20<3890::AID-ANIE3890>3.0.CO;2-T

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