Strong exciton−photon coupling with colloidal quantum dots in a tunable microcavity

Abstract

Polariton emission from optical cavities integrated with various luminophores has been extensively studied recently due to the wide variety of possible applications in photonics, particularly promising in terms of the fabrication of low-threshold sources of coherent emission. Tunable microcavities allow extensive investigation of the photophysical properties of matter placed inside the cavity by deterministically changing the coupling strength and controllable switching from weak to strong and ultra-strong coupling regimes. Here, we demonstrate room-temperature strong coupling of exciton transitions in CdSe/ZnS/CdS/ZnS colloidal quantum dots with the optical modes of a tunable low-mode-volume microcavity. Strong coupling is evidenced by a large Rabi splitting of the photoluminescence spectra depending on the detuning of the microcavity. A coupling strength of 154 meV has been achieved. High quantum yields, excellent photostability, and scalability of fabrication of quantum dots (QDs) pave the way to practical applications of coupled systems based on colloidal QDs in photonics, optoelectronics, and sensing.