Potential energy shift of the Fermi level at plasmonic structures for light-energy conversion determined by graphene-based Raman measurements

Abstract

Single layer graphene was used to determine the electrochemical potential of plasmonic nano-structures for photoelectrochemical energy conversions. From electrochemical Raman measurements of the graphene layer under near-infrared light, illumination has revealed the relationship between the photoenergy conversion ability and the Fermi level of the plasmonic structure. The determination is based on in situ monitoring of G and 2D Raman bands of the graphene layer on plasmonic structures. The correlation plots of G and 2D bands show the dependence on the photoconversion ability. The present electrochemical Raman measurements provide detailed understanding of the plasmon-induced charge transfer process for further developments on the ability.