Abstract
[HIrIVW6O24]7-, representing the first Ir-containing Anderson-Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7- can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives. This journal is
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CITATION STYLE
Adonin, S. A., Izarova, N. V., Besson, C., Abramov, P. A., Santiago-Schübel, B., Kögerler, P., … Sokolov, M. N. (2015). An IrIV-containing polyoxometalate. Chemical Communications, 51(7), 1222–1225. https://doi.org/10.1039/c4cc09271f
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