Oxidative decarboxylative ammonium hypoiodite-catalysed dihydrobenzofuran synthesis

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Abstract

The catalytic use of quaternary ammonium iodides under oxidative conditions allows for the direct conversion of readily available β-ketolactones into dihydrobenzofurans via a decarboxylative oxidative cycloetherification sequence facilitated by an in situ formed ammonium hypoiodite species.

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Röser, K., Scheucher, A., Mairhofer, C., Bechmann, M., & Waser, M. (2022). Oxidative decarboxylative ammonium hypoiodite-catalysed dihydrobenzofuran synthesis. Organic and Biomolecular Chemistry, 20(16), 3273–3276. https://doi.org/10.1039/d2ob00463a

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