Synthesis, characterization and application of high adsorption performance of novel 1,4-polyketone

Abstract

This study aims to develop an alternating polyketone containing cationic groups in one and four alternating positions for increased functionality. A novel polyarylidene ketone was synthesized using simple condensation polymerization of terephthaldehyde and 2,5-hexane dione (PAK) The physicochemical properties of the resulting polymer were evaluated using Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, UV-Visible absorbance, fluorescence, and SEM investigations. The findings show that the polymer is amorphous, has good thermal stability, and emits red light. It can also be used as a dye adsorbent in aqueous solutions, with high selectivity for the cationic dye methylene blue (MB). The adsorbent efficiency of PAK was measured as a function of pH, dosage, and initial dye concentration; the greatest dye removal of 96 % was obtained at pH 10, 50 mg dosage, and initial dye concentration of 20 ppm. Kinetics and isotherms were studied, showing that the pseudo-second-order model described kinetic data better than Freundlich and Langmuir and revealed a satisfactory chemisorption process. This study suggests that PAK can purify MB dyeing wastewater, remove Zn2+, Cu2+, Ni2+, Co2+, Cd2+, Fe3+ metal ions well, and is selective for Fe3+ and Cu2+; ion adsorption is chelating-based.