Thermophysical properties of Th1-xUxO2 pellets prepared by spark plasma sintering technique

Abstract

Th1-xUxO2 solid solutions were synthesized by solid-state reaction and pelletized using the spark plasma sintering (SPS) technique. Pellets with >90% theoretical density were easily obtained within 40 min of sintering without any additive. The thermal conductivity, Young's modulus, Debye temperature, Vickers hardness, and heat capacity were systematically investigated, and the values for ThO2 agree with the literature data. The thermal conductivity of Th1-xUxO 2 decreased with increasing U content up to x =~0.5. This tendency corresponds to phonon-point defect scattering theory. The Young's modulus and Debye temperature linearly decreased with increasing U content. The Debye temperature and standard molar entropy derived from the low-temperature heat capacity agree with the reported values. © 2013 Atomic Energy Society of Japan. All rights reserved.